Effect of the RE (RE = Eu, Er) doping on the structural and textural properties of mesoporous TiO_2 thin films obtained by evaporation induced self-assembly method

摘要

Polymeric sol-gel route has been used for the preparation of TiO_2 and RE_2O_(3-)TiO_2 (RE = Eu, Er) mesoporous thin films by evaporation induced self-assembly method using Si (100) as a substrate. The influence of the relative humidity (RH) on the preparation of the film has been studied being necessary to work under 40％ RH in order to obtain homogeneous and transparent thin films. The films were annealed at different temperatures until 900 ℃/1 h and the anatase crystallization and its crystal size evolution were followed by low angle X-ray diffraction. Neither the anatase-rutile transition nor the formation of other compounds was observed in the studied temperature range. Ellipsoporosimetry studies demonstrated that the thickness of the thin films did not change after calcination at 500 ℃, the porosity was constant until 700 ℃, the pore size increased and the specific surface area decreased with temperature. Moreover, the effect of the doping with Er~(3+) and Eu~(3+) was studied and a clear inhibition of the crystal growth and the sintering process was detected (by transmission electron and atomic force microscopy) when the doped films are compared with the undoped ones. Finally, Eu~(3+) and Er~(3+) f-f transitions were detected by PL measurements.