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Optimizing pyramidal silicon substrates through the electroless deposition of Ag nanoparticles for high-performance surface-enhanced Raman scattering

机译:通过Ag纳米粒子的化学沉积来优化金字塔形硅衬底,以实现高性能的表面增强拉曼散射

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摘要

This work describes the direct fabrication of Ag nanoparticles on pyramidal silicon using a facile, one-step, electroless deposition process at room temperature with short reaction time (3 min). The resulting device could use for rapid drug detection based on surface-enhanced Raman scattering (SEAS). The size of the silicon pyramids controlled by altering the texturing time of the silicon substrate. Spin coating was used to enable the rapid deposition of rhodamine 6G molecules (3 min) on the Ag nanoparticles. The resulting pyramidal silicon decorated with Ag nanoparticles provides large specific area as well as hot spots to promote localized surface plasmon resonance, resulting in notable SEAS enhancement and a low 5-fluorouracil detection limit (10(-6) M).
机译:这项工作描述了在室温下以较短的反应时间(3分钟)使用一种简便的一步式化学沉积工艺直接在金字塔状硅上制备Ag纳米颗粒的方法。所得设备可用于基于表面增强拉曼散射(SEAS)的快速药物检测。硅锥体的尺寸通过改变硅衬底的织构时间来控制。旋涂用于使若丹明6G分子快速沉积(3分钟)在Ag纳米颗粒上。所得的用Ag纳米粒子修饰的金字塔形硅提供较大的比表面积以及热点,以促进局部表面等离子体激元共振,从而显着增强SEAS并降低5-氟尿嘧啶的检出限(10(-6)M)。

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