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Nonconventional treatment of sewage sludge using cement kiln dust for reuse and catalytic conversion of hydrocarbons

机译:使用水泥窑粉尘对烃进行再利用和催化转化的非常规处理

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摘要

Sewage sludge represents a critical environmental issue in Egypt. Large quantities of CKD are emitted from cement factories. It has negative impacts on humans, animals, plants, lands, water, and all remaining environment. It causes serious problems on the national level. Besides using CKD for sludge treatment and reuse as soil conditioner, a new scenario is to use it as catalytic con-vertor of some hydrocarbons. Results showed that CKD is used to separate the organic matters and suspended solids, reduce the organic micropollutants, scavenge heavy metals, and destruct viruses, parasites, and all pathogenic bacteria. The dehydrogenation of isopropanol to acetone and alcohol condensation of the produced acetone to give methyl iso-butyl ketone over different catalyst samples was studied using a flow technique under normal pressure. Results revealed that treatment of raw sludge led to an increase in catalytic activity toward acetone formation by 50 % at 400 ℃. A treatment system was proposed for continuous operation.
机译:污水污泥是埃及的一个关键环境问题。水泥厂排放大量CKD。它对人类,动物,植物,土地,水和所有剩余环境都具有负面影响。它在国家一级造成严重问题。除了将CKD用于污泥处理和作为土壤改良剂再利用外,一种新的方案是将其用作某些碳氢化合物的催化转化器。结果表明,CKD可用于分离有机物和悬浮固体,减少有机物微污染物,清除重金属并破坏病毒,寄生虫和所有病原细菌。使用常压流动技术研究了在不同催化剂样品上异丙醇脱氢成丙酮和生成的丙酮的醇缩合反应生成甲基异丁基酮。结果表明,在400℃下,处理原始污泥可使丙酮的催化活性提高50%。提出了一种连续运行的处理系统。

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