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首页> 外文期刊>The Analyst >Use of simultaneous dual-probemicrodialysis for the determination of pesticide residues in a jade plant (Crassula ovata)
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Use of simultaneous dual-probemicrodialysis for the determination of pesticide residues in a jade plant (Crassula ovata)

机译:同时双探针微渗析法测定玉石植物中的农药残留

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摘要

A microdialysis application for the sampling of plant pesticide residues has been developed utilizingntwo probes with differing perfusate rates simultaneously inserted into symmetric components ofna sampling system. A simple empirical equation is proposed to calculate analyte concentrations inna semi-solid matrix using two different dialysate concentrations. In vitro application yielded excellentncorrelations between the calculated and spiked concentrations. Subsequent in vivo application of thisntechnique for the determination of pesticide distributions in leaves of a jade plant (Crassula ovata)nindicated the utility of this approach in complex living matrices.
机译:已经开发了一种微透析应用,用于采样植物农药残留,使用两种具有不同灌注速率的探针同时插入到采样系统的对称组件中。提出了一个简单的经验方程式,使用两种不同的透析液浓度来计算半固体基质中的分析物浓度。体外应用在计算出的浓度和加标浓度之间产生了极好的相关性。随后该技术在体内用于测定玉石植物(卵形红景天)叶片中农药分布的情况表明该方法在复杂的生物基质中的实用性。

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  • 来源
    《The Analyst》 |2009年第4期|p.748-754|共7页
  • 作者单位

    aDepartment of Chemistry, University of Waterloo, Waterloo, ON, CanadaN2L 3G1. E-mail: janusz@uwaterloo.ca, Fax: +1-519-746-0435, Tel:+1-519-888-4641bDepartment of Biology, University of Waterloo, Waterloo, ON, CanadaN2L 3G1† Electronic supplementary information (ESI) available: tables of MRMparameters and concentration correlations as well as figures ofchromatograms and carbofuran correlation. See DOI: 10.1039/b811700d,;

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