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Risk of misdiagnosis for vinyl chloride non-conformity

机译:对氯乙烯不合格的误诊风险

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In drinking water systems, PVC pipes manufactured prior to 1980 can have a wide range of residual content of vinyl chloride. The leaching of this compound into water may lead to exceed the standards for drinking water quality at consumer's taps, in some cases. Diagnoses have been made since 2012 on points where the non-compliance risk is highest. If the measured concentration is below the standard concentration, one or two samples are enough to classify the point as compliant. However, it was observed that the vinyl chloride concentrations measured on a lot of samples at the same point show a huge variability. This variability can't only be explained by the uncertainty of measurement or by the temperature variation, but also by the heterogeneity of the PVC pipes. The contamination level in water fluctuates unpredictably, depending on the unknown residence time and residual level of vinyl chloride in each PVC pipe. It can be figured that packets of water circulates with various levels of contamination. According to this model, the risk of misdiagnosis with a single sample can be estimated. This risk decreases for warmer water, but the probability to classify this point as compliant whereas it is not, is higher than 20%. Thus, the non-compliance management from a single sample can be criticized because it under-evaluates the long-term risk. Vinyl chloride Diagnosis Variability Drinking water system Standard Non-compliance.
机译:在饮用水系统中,1980年之前制造的PVC管可以具有广泛的氯乙烯残留含量。在某些情况下,将该化合物的浸出量浸入水中可能导致消费者水龙头饮用水质量标准。自2012年以来一直在对非符合风险最高的积分进行诊断。如果测量的浓度低于标准浓度,则一个或两个样品足以将点分类为符合要求。然而,观察到在同一点的大量样品上测量的氯乙烯浓度显示出巨大的变化。这种可变性不能通过测量的不确定度或通过温度变化来解释,而是通过PVC管的异质性来解释。水中的污染水平不可预测地波动,这取决于每个PVC管中的氯乙烯的未知停留时间和残留水平。它可以想到水包与各种污染水平循环。根据该模型,可以估计具有单个样品的误诊的风险。这种风险降低了较温暖的水,但是将这一点分类的概率相当符合,而且它不是高于20%。因此,来自单个样本的非符合性管理可能会受到批评,因为它会估计长期风险。氯乙烯诊断变异饮用水系统标准不合规。

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    《Techniques Sciences Methodes》 |2019年第2期|49-56|共8页
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