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Risk of misdiagnosis for vinyl chloride non-conformity

机译:氯乙烯不合格的误诊风险

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In drinking water systems, PVC pipes manufactured prior to 1980 can have a wide range of residual content of vinyl chloride. The leaching of this compound into water may lead to exceed the standards for drinking water quality at consumer's taps, in some cases. Diagnoses have been made since 2012 on points where the non-compliance risk is highest. If the measured concentration is below the standard concentration, one or two samples are enough to classify the point as compliant. However, it was observed that the vinyl chloride concentrations measured on a lot of samples at the same point show a huge variability. This variability can't only be explained by the uncertainty of measurement or by the temperature variation, but also by the heterogeneity of the PVC pipes. The contamination level in water fluctuates unpredictably, depending on the unknown residence time and residual level of vinyl chloride in each PVC pipe. It can be figured that packets of water circulates with various levels of contamination. According to this model, the risk of misdiagnosis with a single sample can be estimated. This risk decreases for warmer water, but the probability to classify this point as compliant whereas it is not, is higher than 20%. Thus, the non-compliance management from a single sample can be criticized because it under-evaluates the long-term risk. Vinyl chloride Diagnosis Variability Drinking water system Standard Non-compliance.
机译:在饮用水系统中,1980年之前生产的PVC管的氯乙烯残留量范围很广。在某些情况下,将这种化合物浸入水中可能会超出消费者自来水的饮用水质量标准。自2012年以来,已经对违规风险最高的地方进行了诊断。如果测得的浓度低于标准浓度,则一个或两个样品足以将该点分类为顺应性。然而,观察到在同一点的许多样品上测得的氯乙烯浓度显示出巨大的变化性。这种可变性不仅可以通过测量的不确定性或温度变化来解释,还可以通过PVC管的异质性来解释。水中的污染水平会意外地波动,具体取决于未知的停留时间和每条PVC管中氯乙烯的残留水平。可以看出,水包在各种污染水平下循环。根据该模型,可以估计单个样品的误诊风险。对于较温暖的水,此风险会降低,但将此点分类为“符合”(而不是“符合”)的可能性高于20%。因此,由于单个样本的不合规管理会低估长期风险,因此可能会受到批评。氯乙烯诊断变异性饮用水系统标准不合规。

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    《Techniques Sciences Methodes》 |2019年第2期|49-56|共8页
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