Syntheses, crystal structures and thermal behavior of three Mn(II) complexes with 4-acyl pyrazolone derivatives

摘要

Three new manganese complexes, [Mn(PPeAP-INH)(CH3OH)2]n(CHCl3) (1) [PPeAP-INH=N-(1-phenyl-3-phenylethyl-4-ethylene-5-pyrazolone isoniazid, INH = isoniazid], [Mn2(PM4MbP-INH)2(CH3OH)4](CH3OH) (2·CH3OH), [PM4MbP-INH=N-(1-phenyl-3-methyl-4-(p-methylbenzoylene)-5-pyrazolone) isoniazid)] and [Mn2(PPePeP-INH)2(CH3OH)4] (3) [PPePeP-INH=N-(1-phenyl-3-phenylethyl-4-phenylethylene-5-pyrazolone) isoniazid] have been prepared, aiming at the formation of extended coordination polymer with Mn(II) ions. Formation of the corresponding manganese-ligand complexes has been monitored and characterized by chemical and spectroscopic techniques. X-ray diffraction analyses of available single crystals revealed 1D polymeric patterns of supramolecular system. Among them, the dimers of 2 and 3, bridged by two methanol molecules, are extended by hydrogen bond of O–H···N to form the 1D chain. In these three new complexes which are all octahedral coordination environments, the N(5) atom of the pyridine heterocycles plays a very important role in building the bridged polymeric chain.