Composition of the Wax Fraction of Bitumen from Methylated Brown Coals

摘要

Changes in the group and individual compositions of the wax fractions of bitumen in the course of brown coal methylation were studied. With the use of IR and NMR spectroscopy and chromatography-mass spectrometry, it was found that the esters of methylated coal waxes consisted of the native esters of fatty acids and the methyl esters of these acids formed as a result of an alkylation treatment. Esterification and transester-ification were predominant among the reactions of aliphatic fraction components. A positive effect of methanol alkylation on an increase in the yield of the aliphatic fractions of was found.