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Production of porous carbon materials from bark

机译:从树皮生产多孔碳材料

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摘要

The effect of the conditions of consecutive carbonization-activation of the bark of larch, fir tree, and birch in a fluidized bed reactor on the yield, textural characteristics, and sorption properties of the resulting porous carbon materials was studied. The rate of temperature increase at the stage of the pyrolysis of bark exerted the greatest effect on the specific surface area, total pore volume, and sorption capacity of porous carbon materials for iodine and methylene blue. The porous carbon materials obtained by the slow pyrolysis (5 K/min) of larch bark with an isothermal exposure for 60 min at 600A degrees C and the subsequent activation with CO2 at 850A degrees C for 30 min were characterized by a maximum sorption activity. The porous carbon materials obtained from bark by consecutive carbonization-activation in a fluidized bed were similar to commercial powder sorbents from wood in their characteristics.
机译:研究了流化床反应器中落叶松,枞树和桦树皮的连续碳化活化条件对所得多孔碳材料的产率,组织特性和吸附性能的影响。树皮热解阶段的升温速率对比表面积,总孔体积和多孔碳材料对碘和亚甲基蓝的吸附能力影响最大。通过落叶松树皮的缓慢热解(5 K / min),在600A的温度下等温暴露60分钟,然后在850 A的温度下用CO2活化30分钟而获得的多孔碳材料,具有最大的吸附活性。通过在流化床中连续进行碳化活化而从树皮中获得的多孔碳材料,其特性与木材中的商用粉末吸附剂相似。

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  • 来源
    《Solid Fuel Chemistry 》 |2015年第5期| 278-288| 共11页
  • 作者单位

    Russian Acad Sci, Inst Chem & Chem Technol, Siberian Branch, Krasnoyarsk, Russia|Siberian Fed Univ, Krasnoyarsk, Russia;

    Russian Acad Sci, Inst Chem & Chem Technol, Siberian Branch, Krasnoyarsk, Russia|Siberian Fed Univ, Krasnoyarsk, Russia;

    Russian Acad Sci, Inst Chem & Chem Technol, Siberian Branch, Krasnoyarsk, Russia;

    Russian Acad Sci, Inst Chem & Chem Technol, Siberian Branch, Krasnoyarsk, Russia|Siberian Fed Univ, Krasnoyarsk, Russia;

    Russian Acad Sci, Inst Chem & Chem Technol, Siberian Branch, Krasnoyarsk, Russia;

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