Probing the Threshold to H Atom Transfer Along a Hydrogen-Bonded Ammonia Wire

摘要

We characterized the entrance channel, reaction threshold, and mechanism of an excited-state H atom transfer reaction along a unidirectionally hydrogen-bonded "wire" -O-H···NH_3···NH_3···NH_3···N. Excitation of supersonically cooled 7-hydroxyquinoline-(NH_3)_3 to its vibrationless S_1 state produces no reaction, whereas excitation of ammonia-wire vibrations induces H atom transfer with a reaction threshold ≈ 200 wave numbers. Further translocation steps along the wire produce the S_1 state 7-ketoquinoline·(NH_3)_3 tautomer. Ab initio calculations show that proton and electron movement along the wire are closely coupled. The rate-controlling S_1 state barriers arise from crossings of a ππ* with a Rydberg-type πσ* state.