A shear rheometer for measuring shear stress and both normal stress differences in polymer melts simultaneously: the MTR 25

摘要

The MTR 25 is a multitask rheometer (for shear and squeeze flow) with 25 kg of normal force and a partitioned plate. Torque and normal force are measured at both, the inner disk and the outer ring of the plate. The first and second normal stress differences can be determined from a single test. The axial stiffness is high (107 N/m) by using rigid springs and strain gauges for the load cell. Monodisperse polystyrene (M _w = 206 kg/mol, 180°C) has been sheared in the range from 0.05 to 47 s − 1. The viscosity and first normal stress difference are highly reproducible. The second normal stress difference scatters and mirrors the instability at the rim. A critical comparison is made between the MTR 25 method and the single transducer evaluation method (RMS 800 method, Schweizer, Rheol Acta 41:337–344, 2002): Both yield excellent and coinciding viscosity and first normal stress difference data. The RMS 800 method gives more stable second normal stress difference data, since the normal force from the outer ring, which is influenced by edge fracture, is not used. Data for the RMS 800 method can be acquired on the MTR 25. The high normal force capacity permits larger samples and higher shear rates than on the RMS 800.