Alkene epoxidations catalysed by Mo(VI) supported on Merrifield's polymer

S. Gil; R. Gonzalez; R. Mestres

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Alkene epoxidations catalysed by Mo(VI) supported on Merrifield's polymer

机译：负载在Merrifield聚合物上的Mo（VI）催化的烯烃环氧化

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摘要

High conversion and epoxide selectivity from alkenes is acheived with tert-butyl hydroperoxide and a polystyrene-grafted Mo(VI) catalyst, with no noticeable leaching of Mo from the support.

机译：用叔丁基氢过氧化物和聚苯乙烯接枝的Mo（VI）催化剂可实现从烯烃的高转化率和环氧化物选择性，而Mo不会从载体中明显浸出。

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来源
《Reactive & Functional Polymers》 |1999年第1期|p.65-72|共8页
作者
S. Gil; R. Gonzalez; R. Mestres;
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作者单位

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类高分子化合物产品;
关键词
Epoxidation; Molybdenum (VI)-supported catalyst;

机译：环氧化;钼（VI）负载的催化剂;

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专利

1. ALKENE EPOXIDATIONS CATALYSED BY MO(VI) SUPPORTED ON IMIDAZOLE-CONTAINING POLYMERS .2. RECYCLING OF POLYBENZIMIDAZOLE-SUPPORTED MO(VI) IN THE EPOXIDATION OF CYCLOHEXENE [J] . Miller MM., Sherrington DC. Journal of Catalysis . 1995,第2期

机译：由Mo（VI）催化的烯烃环氧化支持含咪唑的聚合物.2。环己烯环氧化中的聚苯和咪唑负载的MO（VI）的再循环
2. ALKENE EPOXIDATIONS CATALYSED BY MO(VI) SUPPORTED ON IMIDAZOLE-CONTAINING POLYMERS .1. SYNTHESIS, CHARACTERISATION, AND ACTIVITY OF CATALYSTS IN THE EPOXIDATION OF CYCLOHEXENE [J] . Miller MM., Sherrington DC. Journal of Catalysis . 1995,第2期

机译：含咪唑聚合物的MO（VI）催化的烯烃环氧化1。环己烯环氧化中催化剂的合成，表征及活性
3. Optimisation of alkene epoxidation catalysed by polymer supported Mo(VI) complexes and application of artificial neural network for the prediction of catalytic performances [J] . Misbahu Ladan Mohammed, Dipesh Patel, Rene Mbeleck Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications . 2013,第Null期

机译：聚合物负载的Mo（VI）配合物催化的烯烃环氧化反应的优化及人工神经网络在催化性能预测中的应用
4. Trends in Alkene Insertion in Late-and Early Transition Metal Compounds: Relevance to Transition Metal-Catalyzed Polymerization of Polar Vinyl Monomers [C] . Myeongsoon Kang, Ayusman Sen, Lev Zakharov, Symposium on beyond metallocenes: Next-generation polymerization catalysts . 2003

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5. Bimetallic effects in the homopolymerization of styrene and copolymerization of ethylene and styrenic comonomers. Scope, kinetics, and mechanism/catalytic in situ synthesis of high energy storage density metal oxide-polyolefin nanocomposites using supported metallocenes. Systematics of nanoparticle, shape, and interfacial characteristics on leakage current density, permittivity, and breakdown strength [D] . Guo, Neng 2007

机译：苯乙烯均聚以及乙烯与苯乙烯共聚单体共聚中的双金属作用。使用负载型茂金属的高能量存储密度金属氧化物-聚烯烃纳米复合材料的范围，动力学和机理/催化原位合成。纳米粒子，形状和界面特性对漏电流密度，介电常数和击穿强度的影响
6. Microwave Assisted Regioselective Bromomethoxylation of Alkenes Using Polymer Supported Bromine Resins [O] . Geetha Gopalakrishnan, Viswanathan Kasinath, N.D. Pradeep Singh, 2002

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7. Greener alkene epoxidations via use of novel polymer-supported Mo(VI) catalysts in a continuous reactive distillation process [O] . Ambroziak Krzysztof, Mbeleck Rene, Saha Basu, 2009

机译：通过在连续反应蒸馏过程中使用新型聚合物负载的Mo（VI）催化剂，实现更绿色的烯烃环氧化
8. Comparison of the Photocatalytic Behavior of Phosphinated Polymer-Anchored Iron Carbonyl Species and Homogeneous Phosphine Substituted Iron Carbonyl Species: Alkene Isomerization and Reaction with Trialkylsilanes. [R] . Sanner, R. D., Austin, R. G., Wrighton, M. S., 1979

机译：磷化聚合物 - 锚定羰基铁与均相膦取代羰基铁的光催化性能比较：烯烃异构化反应与三烷基硅烷反应。

Alkene epoxidations catalysed by Mo(VI) supported on Merrifield's polymer

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