Synthesis and characterization of poly(acrylaminophosphonic-carboxyl-hydrazide) chelating fibre____________________________

摘要

The poly(acrylaminophosphonic-carboxyl-hydrazide) chelating ion exchange fibre was prepared by the amination and phosphorization reaction of the hydrazine-modified polyacrylonitrile fibre. The structure fothe chelating fibre and the same fibre saturated by Cu(II) and Ag(I) ions was investigated by IR spectrometer in detail. In addition, the crystaline and surface characteristics of the chelating fibre were determined by X-ray diffraction and SEM. The higher binding capacities of the fibrous sorbent for Cu(II), Pb(II), Zn(II), Co(II), Hg(II), Cd(II), Mn(II), Cr(II) and Ag(I) and the effect of pH value on adsorption of the clelating fibre for Cu(II) and Hg(II) ions were examined.