Poly(ionic liquid) prepared by photopolymerization of ionic liquid monomers as quasi-solid-state electrolytes for dye-sensitized solar cells

摘要

Vinylimidazolium-typed poly(ionic liquids) (PILs) are prepared by photo-polymerization of ionic liquid monomers. Vinylimidazolium-based ionic liquid monomers with C4 and C8 alkyl tail length were synthesized via quaternization of 1-vinylimidazole with corresponding n-alkyl bromides. Polymerization was conducted at a 3 wt.% of photoinitiators in these monomers using illumination of 36 W LED light In the same procedure, preparation of cross-linked PILs was performed in the presence of 15 mol% of divinylimidazolium-based cross-linker. These PILs are characterized by using chemical structure, physical characteristics, and electrical conductivity. Electrical conductivity of C-4-based PILs is greater than that of C-8-based PILs, whereas linear PILs are higher than crosslinked PILs. Crosslinked PILs have higher glass transition and thermal decomposition temperatures as compared linear PILs. PILs consist of the repeating units of anion and cation pair. Its nature has moderate electronic conductivity, which is suitable use in gel-type or quasi-solid-state dye-sensitized solar cells (DSSCs). The linear PILs were incorporated in DSSCs obtaining an efficient quasi-solid-state cell to solve the leakage of liquid electrolyte in a liquid-type DSSC. (C) 2016 Elsevier B.V. All rights reserved.