Crystal structures and magnetic properties of cyano-bridged 4f-3d complexes

摘要

The most recent research progress in the fields of the crystal structure and magnetochemistry for rate earth-transition metal cyano - bridged complexes is reviewed in detail. The emphasis is put on the introduction to the re- search achievements of our group in this field, including all the types of complexes with different crystal structures in these systems such as dinuclear, trinuclear, one-dimensional chain and hydrogen-bonded network ion-pairs. At the same time a few examples of rare earth-transition metal molecular-based magnets have been found to exhibit excellent magneto chemical properties, such as the long-range magnetic ordering, the higher critical temperature T_c and the stronger coer- cive force. These results will be expected to promote the research development in this field.