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A comparison of electricity and hydrogen production systems with CO_2 capture and storage. Part A: Review and selection of promising conversion and capture technologies

机译:电力和制氢系统与CO_2捕获和存储的比较。 A部分:审查和选择有前途的转换和捕获技术

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We performed a consistent comparison of state-of-the-art and advanced electricity and hydrogen production technologies with CO_2 capture using coal and natural gas, inspired by the large number of studies, of which the results can in fact not be compared due to specific assumptions made. After literature review, a standardisation and selection exercise has been performed to get figures on conversion efficiency, energy production costs and CO_2 avoidance costs of different technologies, the main parameters for comparison. On the short term, electricity can be produced with 85-90% CO_2 capture by means of NGCC and PC with chemical absorption and IGCC with physical absorption at 4.7-6.9 ?ct/kWh, assuming a coal and natural gas price of 1.7 and 4.7 ?/GJ. CO_2 avoidance costs are between 15 and 50 ?/t CO_2 for IGCC and NGCC, respectively. On the longer term, both improvements in existing conversion and capture technologies are foreseen as well as new power cycles integrating advanced turbines, fuel cells and novel (high-temperature) separation technologies. Electricity production costs might be reduced to 4.5-5.3 ?ct/kWh with advanced technologies. However, no clear ranking can be made due to large uncertainties pertaining to investment and O&M costs. Hydrogen production is more attractive for low-cost CO_2 capture than electricity production. Costs of large-scale hydrogen production by means of steam methane reforming and coal gasification with CO_2 capture from the shifted syngas are estimated at 9.5 and 7 ?/GJ, respectively. Advanced autothermal reforming and coal gasification deploying ion transport membranes might further reduce production costs to 8.1 and 6.4 ?/GJ. Membrane reformers enable small-scale hydrogen production at nearly 17 ?/GJ with relatively low-cost CO_2 capture.
机译:在大量研究的启发下,我们对最先进的,先进的电力和制氢技术与使用煤和天然气进行CO_2捕集进行了一致比较,但由于具体的研究结果,实际上无法进行比较作出的假设。经过文献综述后,已进行了标准化和选择工作,以获取有关不同技术的转换效率,能源生产成本和避免CO_2成本的数据,这些数据是比较的主要参数。从短期来看,假设煤和天然气的价格分别为1.7和4.7,则通过NGCC和PC的化学吸收和IGCC的物理吸收为4.7-6.9 µct / kWh时,可以捕获85-90%的CO_2。 ?/ GJ。 IGCC和NGCC的CO_2避免成本分别为15至50?/ t CO_2。从长远来看,可以预见的是,现有转换技术和捕集技术都将得到改善,以及集成了先进涡轮机,燃料电池和新型(高温)分离技术的新动力循环。用先进的技术可以将电力生产成本降低到4.5-5.3 ct / kWh。但是,由于与投资和运维成本有关的不确定性很大,因此无法进行清晰的排名。与低成本生产相比,氢气生产对于低成本CO_2捕获更具吸引力。通过蒸汽甲烷重整和从转化后的合成气中捕集CO_2进行煤气化而进行大规模制氢的成本分别估计为9.5和7 L / GJ。先进的自热重整和采用离子迁移膜的煤气化可以进一步将生产成本降低至8.1和6.4?/ GJ。膜重整器能够以相对较低的CO_2捕集量以接近17 l / GJ的规模生产氢气。

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