Photophysical and photochemical properties of dithiolate-diimine zinc complexes: Complexes with 3,4-toluenedithiolate ligand: (tdt)Zn(bpy) (tdt)Zn(phen), (tdt)Zn(biqu)

A Z NOY; A M GALIN; YU V RAZSKAZOVSKII; M YA MELNIKOV

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Photophysical and photochemical properties of dithiolate-diimine zinc complexes: Complexes with 3,4-toluenedithiolate ligand: (tdt)Zn(bpy) (tdt)Zn(phen), (tdt)Zn(biqu)

机译：二硫代-二亚胺锌配合物的光物理和光化学性质：具有3,4-甲苯二硫代配体的配合物：（tdt）Zn（bpy）（tdt）Zn（phen），（tdt）Zn（biqu）

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Photochemistry and photophysics of dithiolate-diimine zinc complexes with the lowest ligand-to-ligand charge transfer (LLCT) excited state were studied. Investigated complexes were found to be nonluminescent because LLCT transition is symmetry-forbidden. Steady-state and flash photolysis experiments indicate that LLCT* state of these complexes can reduce methylviologen and oxygen.

机译：研究了具有最低配体-配体电荷转移（LLCT）激发态的二硫代-二亚胺锌配合物的光化学和光物理性质。发现研究的复合物是不发光的，因为LLCT过渡是对称禁止的。稳态和快速光解实验表明，这些配合物的LLCT *状态可以还原甲基紫精和氧气。

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来源
《Proceedings of the Indian Academy of Sciences. Chemical Sciences》 |1995年第6期|p.789-794|共6页
作者
A Z NOY; A M GALIN; YU V RAZSKAZOVSKII; M YA MELNIKOV;
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作者单位

Department of Chemistry, Moscow State University, 119899, Moscow, Russia;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
中图分类化学;
关键词
Photoinduced electron transfer; LLCT; dithiolate-diimine zinc complexes;

机译：光诱导电子转移LLCT二硫代二亚胺锌配合物;
入库时间 2022-08-18 00:38:41

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Photophysical and photochemical properties of dithiolate-diimine zinc complexes: Complexes with 3,4-toluenedithiolate ligand: (tdt)Zn(bpy) (tdt)Zn(phen), (tdt)Zn(biqu)

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