Synthesis and X-ray powder diffraction data of 7-fluoro-2-exo- (2-methylpropen-1-yl)-2,3,4,5-tetrahydro-1,4-epoxybenzo[d]azepine

M. A. Macfas; J. A. Henao; Una Maria Acosta; Alirio Palma

首页> 外文期刊>Powder diffraction >Synthesis and X-ray powder diffraction data of 7-fluoro-2-exo- (2-methylpropen-1-yl)-2,3,4,5-tetrahydro-1,4-epoxybenzo[d]azepine

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Synthesis and X-ray powder diffraction data of 7-fluoro-2-exo- (2-methylpropen-1-yl)-2,3,4,5-tetrahydro-1,4-epoxybenzo[d]azepine

机译：7-氟-2-异-（2-甲基丙烯-1-基）-2,3,4,5-四氢-1,4-环氧苯并[d] a庚因的合成及X射线粉末衍射数据

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摘要

The stereoselective synthesis of 7-fluoro-2-exo-(2-methylpropen-1-yl)-2,3,4,5-tetrahydro-l,4-epoxy-benzo[b]azepine was developed by intramolecular 1,3-dipolar cycloaddition of the nitrone derived from the corresponding 2-allyl-4-fluoro-N-(3-methylbut-2-enyl)aniline. The X-ray powder diffraction (XRPD) pattern for the new compound was analyzed and found to crystallize in a monoclinic system with space group P2_1/m (No. 11) and refined unit-cell parameters a= 11.655(5) A, b = 5.850(2) A, c = 18.314(4) A, B= 104.27(3) and V= 1210.1 (6) A~3.

机译：分子内1,3合成了7-氟-2-外-（2-甲基丙烯-1-基）-2,3,4,5-四氢-1,4-环氧-苯并[b]氮杂的立体选择性合成方法衍生自相应的2-烯丙基-4-氟-N-（3-甲基丁-2-烯基）苯胺的硝酮的-偶极环加成。分析了该新化合物的X射线粉末衍射（XRPD）图谱，发现该结晶在空间群P2_1 / m（第11号）和精确的晶胞参数a = 11.655（5）A，b的单斜晶系统中结晶。 = 5.850（2）A，c = 18.314（4）A，B = 104.27（3），V = 1210.1（6）A〜3。

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来源
《Powder diffraction》 |2013年第1期|49-52|共4页
作者
M. A. Macfas; J. A. Henao; Una Maria Acosta; Alirio Palma;
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作者单位

Grupo de Investigation en Quimica Estructural (GIQUE), Escuela de Quimica, Facultad de Ciencias, Universidad Industrial de Santander, A.A. 678, Carrera 27, Calle 9 Ciudadela Universitaria, Bucaramanga, Colombia;

Grupo de Investigation en Quimica Estructural (GIQUE), Escuela de Quimica, Facultad de Ciencias, Universidad Industrial de Santander, A.A. 678, Carrera 27, Calle 9 Ciudadela Universitaria, Bucaramanga, Colombia;

Laboratorio de Sintesis Orgdnica (ISO), Escuela de Quimica, Facultad de Ciencias, Universidad Industrial de Santander, A.A. 678, Carrera 27, Calle 9, Ciudadela Universitaria, Bucaramanga, Colombia;

Laboratorio de Sintesis Orgdnica (ISO), Escuela de Quimica, Facultad de Ciencias, Universidad Industrial de Santander, A.A. 678, Carrera 27, Calle 9, Ciudadela Universitaria, Bucaramanga, Colombia;

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收录信息美国《科学引文索引》(SCI);美国《生物学医学文摘》(MEDLINE);
原文格式 PDF
正文语种 eng
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关键词
1, 4-Epoxytetrahydrobenzoazepines; antiparasitic activity; X-ray powder diffraction data;

机译：1;4-环氧四氢苯并a庚因;抗寄生虫活性X射线粉末衍射数据;

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Synthesis and X-ray powder diffraction data of 7-fluoro-2-exo- (2-methylpropen-1-yl)-2,3,4,5-tetrahydro-1,4-epoxybenzo[d]azepine

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