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The Stabilization Effect of Tris(hydroxymethyl)aminomethane and Oxidation of Carbon Black on the Resistivity-Temperature Character of Carbon Black-Filled Polyethylene

机译:三(羟甲基)氨基甲烷的稳定作用和炭黑的氧化作用对炭黑填充聚乙烯的电阻率-温度特性的影响

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摘要

Carbon black (CB)-filled high density polyethylene (HDPE) composites, incorporating with or without tris(hydroxymethyl)aminomethane (Tris), were prepared by melt blending. The effects of CB oxidation and Tris incorporation on the resistivity-temperature characters were studied. The negative temperature coefficient effect (NTC) effect and the isothermal variation of resistance with time were reduced by incorporating Tris, and oxidation of CB enhanced the effects of Tris addition. The reason lies in the increase of polarity resulting from CB oxidation and the interaction between Tris and CBs.
机译:通过熔融共混制备含或不含三(羟甲基)氨基甲烷(Tris)的炭黑(CB)填充高密度聚乙烯(HDPE)复合材料。研究了CB氧化和Tris掺入对电阻率-温度特性的影响。通过掺入Tris,可降低负温度系数效应(NTC)效应和电阻随时间的等温变化,而CB的氧化作用可增强Tris添加的效应。原因在于CB氧化和Tris与CB之间的相互作用导致极性增加。

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  • 来源
    《Polymer-Plastics Technology and Engineering》 |2010年第14期|p.1473-1477|共5页
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  • 作者单位

    Department of Polymer Science and Engineering, Zhejiang University, and Key Laboratory of Macromolecular Synthesis and Functionalization, Ministry of Education, Hangzhou, China;

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