Irradiation Modification of PVC/NBR Blend

摘要

Electron beam initiated cross-linking on the 50/50 poly(vinyl chloride), PVC/acrylonitrile butadiene rubber, NBR blend was studied in the absence and presence of 4 phr trimethylolpropane triacrylate (TMPTA). The 50/50 NBR/PVC blend was prepared by mixing in a Brabender Plasticoder at 170°C. The blend was then irradiated by using a 3.0 MeV electron beam machine at doses ranging from 0 to 200 kGy in air and room temperature. The changes in gel fraction, tensile strength, hardness, impact strength, scanning electron micrographs and dynamic mechanical properties of the samples were investigated. The gel fraction results indicate that under the irradiation conditions employed, the PVC/NBR blend cross-linked by electron beam irradiation. The addition of TMPTA was found to be effective in the acceleration of the radiation-induced cross-linking. Gradual increases in mechanical properties with irradiation dose were observed before exhibiting a decline due to embrittlement as a consequence of excessive cross-linking at higher irradiation doses. The gradual changeover from ductile to brittle fracture due to the irradiation-induced cross-linking was evident from the SEM examination The increase in the storage modulus and T_g as well as the reduction in the damping peak with the increase in irradiation dose reveal that the enhancement in mechanical properties of NBR/PVC blends upon irradiation is due to the irradiation-induced cross-linking, as well as the improved interaction between NBR and PVC.