Pyrolysis mechanism of polyimide containing bio-molecule adenine building block

摘要

The pyrolysis mechanism and pyrolysis behavior of adenine-containing polyimide (API) were studied by thermogravimetric analyzer with Fourier transform infrared analysis and mass spectrometry (TG-FTIR-MS) and pyrolysis-gas chromatography-mass spectroscopy (Py-GC-MS). TG-FTIR-MS and Py-GC-MS were employed to continuously track the release of volatile products during the pyrolysis process. Thermogravimetric analysis (TG) indicated that API presented outstanding thermal stability. Additionally, it was observed that the volatile products were formed during the pyrolysis of API, including CO_2, CO, HCN, benzonitrile, aniline and phenyl isocyanate. A probable pyrolysis mechanism of the API has been proposed according to the results of TG-FTIR-MS and Py-GC-MS.