Highly efficient organic light-emitting diodes employing the periodic micro-structured ITO substrate fabricated by holographic lithography

摘要

The optical waveguide effect limits strongly the light out-coupling efficiency in organic light-emitting diodes (OLEDs). Patterning the transparent ITO anode on the substrate is a potential way to weaken the optical waveguide effect and enhance the light-emitting efficiency of OLEDs. Herein, the one-dimensional (ID) and two-dimensional (2D) periodic patterned ITO/glass substrates have been successfully fabricated by using the holographic lithography technology and used to fabricate highly efficient OLEDs. The periodic micro-structured ITO layer could manipulate the total internal reflection at the organic/ITO interfaces and enhance the scattering effect so as to improve the light out-coupling efficiency. The effect of different micro-structured ITO layers on the light-emitting efficiency was investigated in a kind of orange phosphorescent OLEDs based on the m-MTDATA:Ir (Flpy-CF_3)_3/TmPyPB emissive layer. The orange OLEDs employing the ID grating and 2D lattice patterned HO/ glass substrates show the external quantum efficiencies (EQEs) of 25.12% and 29.61%, respectively. The orange OLEDs fabricated with the 2D hole patterned ITO glass substrate demonstrate the best light-emitting performance with a current efficiency of 100.55 cd A~(-1), an EQE of 31.39% and a power efficiency of 121.50 lm W~(-1), respectively.