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Cross β-alkylation of primary alcohols catalysed by DMF-stabilized iridium nanoparticles

机译:通过DMF稳定的铱纳米粒子催化的伯醇的交叉β-烷基化

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摘要

A simple method for the cross p-alkylation of linear alcohols with benzyl alcohols in the presence of DMF-stabilized iridium nano-particles was developed. The nanoparticles were prepared in one-step and thoroughly characterized. Furthermore, the optimum reaction conditions have a wide substrate scope and excellent product selectivity.
机译:发育了一种在DMF稳定的铱纳米颗粒存在下用苄醇与苄醇的线性醇的交叉p烷基化的简单方法。纳米颗粒在一步中制备并彻底表征。此外,最佳反应条件具有宽的基材范围和优异的产品选择性。

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  • 来源
    《Organic & biomolecular chemistry》 |2021年第9期|1950-1954|共5页
  • 作者单位

    Department of Chemistry and Materials Engineering Faculty of Chemistry Materials and Bioengineering Kansai University Suita Osaka 564-8680 Japan;

    Department of Chemistry and Materials Engineering Faculty of Chemistry Materials and Bioengineering Kansai University Suita Osaka 564-8680 Japan;

    Comprehensive Analysis Center The Institute of Scientific and Industrial Research (ISIR) Osaka University 8-1 Mihogaoka Ibaraki Osaka 567-0057 Japa;

    Department of Chemistry and Materials Engineering Faculty of Chemistry Materials and Bioengineering Kansai University Suita Osaka 564-8680 Japan;

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