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Formation of graphene nanosheets/epoxy resin composite and study its structural, morphological and nonlinear optical properties

机译:石墨烯纳米片/环氧树脂复合材料的形成及其结构,形态和非线性光学性质的研究

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摘要

The attention towered the fabrication of graphene nanosheets/polymer composites have gradually boosted in the scientific research since these systems have exhibited improved thermal and mechanical stabilities and nonlinear optical properties compared to the pristine polymer. Herein, graphene nanosheets (GNS) were firstly synthesized through liquid phase exfoliation (LPE) of graphite in isopropanol then mixed with epoxy resin (ER) creating a composite of GNS/ER. The properties of the as-obtained structure were evaluated by transmission electron and ultraviolet-visible spectroscopies. The nonlinear optical properties (NLO) of GNS/ER were investigated through single beam Z-scan technique using a continuous-wave (CW) laser beam obtained from a solid-state laser (SDL). The results reveal that GNS/ER composite shows a negative nonlinear refractive index of (-0.26 x 10(-8) cm(2)/W). Optical limiting (OL) measurements were performed on the GNS/ER and the mechanism of the OL is ascribed to the nonlinear refraction (thermal effects). These outcomes specify the potential use of cost-effective produced GNS/ER composite to boost the NLO and OL for future photonic applications.
机译:石墨烯纳米片/聚合物复合材料的制造引起了人们的极大关注,因为与原始聚合物相比,这些系统已显示出改善的热稳定性和机械稳定性以及非线性光学性质,这在科学研究中已逐渐得到增强。在本文中,首先通过在异丙醇中对石墨进行液相剥离(LPE)合成石墨烯纳米片(GNS),然后将其与环氧树脂(ER)混合,制成GNS / ER的复合材料。通过透射电子和紫外-可见分光光度法评价所得结构的性质。使用从固态激光器(SDL)获得的连续波(CW)激光束,通过单束Z扫描技术研究了GNS / ER的非线性光学特性(NLO)。结果表明,GNS / ER复合材料的负非线性折射率为(-0.26 x 10(-8)cm(2)/ W)。在GNS / ER上进行了光学极限(OL)测量,并且OL的机理归因于非线性折射(热效应)。这些成果表明,可以潜在地使用具有成本效益的GNS / ER复合材料来增强NLO和OL,以用于未来的光子应用。

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