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Dissociation dynamics of the low-lying Rydberg states of Xe2: a velocity map imaging study

机译:Xe 2 的低里德堡态的解离动力学:速度图成像研究

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The photodissociation dynamics of Xe2 Rydberg states in the 76,900-80,000 cm−1 region have been studied using a combination of resonance enhanced multi-photon ionization and velocity map imaging. By monitoring photodissociation product channels as a function of excitation energy, several localized and long range perturbations of the excited states have been identified. In addition, several new band systems have been observed and assigned as the Xe2 5d 2[1/2]0°  ← X , 5d 2[1/2]1°  ← X , 5d 2[3/2]2°  ← X , and 5d 2[7/2]3°  ← X transitions.View full textDownload full textKeywordsxenon dimer, rare gas complexes, Xe2 , Xe2 + , photodissociation, velocity map imaging, van der WaalsRelated var addthis_config = { ui_cobrand: "Taylor & Francis Online", services_compact: "citeulike,netvibes,twitter,technorati,delicious,linkedin,facebook,stumbleupon,digg,google,more", pubid: "ra-4dff56cd6bb1830b" }; Add to shortlist Link Permalink http://dx.doi.org/10.1080/00268976.2012.698027
机译:Xe 2 Rydberg态在76,900-80,000cm ˆ1 区域的光解离动力学是通过共振增强多光子电离和速度图成像。通过监测光解产物通道作为激发能的函数,已经确定了激发态的几个局部和远距离扰动。此外,已观察到几个新的波段系统,并将其分配为Xe 2 5d 2 [1/2] 0 °° X,5d 2 [1/2] 1 °°X,5d 2 [3/2] 2 °X和5d 2 [7/2] 3 °°X过渡。查看全文下载全文关键字氙二聚体,稀有气体络合物,Xe2,Xe2 +,光解离,速度图成像,范德华力相关var addthis_config = {在线”,services_compact:“ citeulike,netvibes,twitter,technorati,可口,linkedin,facebook,stumbleupon,digg,google,更多”,发布号:“ ra-4dff56cd6bb1830b”};添加到候选列表链接永久链接http://dx.doi.org/10.1080/00268976.2012.698027

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