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Transesterification of Kapok Seed Oil (Ceiba pentandra) Using Heterogeneous Catalyst Bimetallic Oxide of Zinc and Copper Supported by γ-Alumina

机译:利用γ-氧化铝支持的锌和铜的非均相催化剂二金属氧化物酯化酯化

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摘要

Biodiesel was produced from Kapok seed (Ceiba pentandra) oil (KSO) using heterogeneous bimetallic oxide of copper and zinc supported by γ-alumina. The Alumina-supported copper oxide- zinc oxide (CuO- ZnO γ /- Al_2O_3) further notated by ACZ was synthesized using precipitation, impregnation and gel methods. It also was characterized using the X-ray diffraction (X-RD), and Brunauwer-Emmett Teller (BET) methods. Before being transesterified, KSO was subjected to pretreatment with the aim of minimizing gum and other impurities and reducing the concentration of free fatty acids. The activity test of ACZ catalyst was done by introducing it through the transesterification process of KSO with methanol. The transesterification process was carried out in a laboratory scale three neck flask. The effect of calcinating temperature (°C), and calcinating time of catalyst (h) on the yield of fatty acid methyl ester (FAME) were studied, respectively. The results revealed that the kapok seed oil was worthy and potentially to transesterified into biodiesel using ACZ catalyst with highest FAME yield of 46.67%.
机译:使用由γ-氧化铝负载的铜和锌的非均相双金属氧化物从Kapok Seed(Ceiba Pentandra)油(KSO)生产生物柴油。使用沉淀,浸渍和凝胶方法合成通过ACZ进一步注意的氧化铝载氧化铜氧化锌(CuO-ZnOγ/ - Al_2O_3)。它还使用X射线衍射(X-RD)和Brunauwer-Emmett Teller(Bet)方法的特征。在酯化之前,kso经受预处理,目的是最小化口香糖和其他杂质并降低游离脂肪酸的浓度。通过将KSO的酯交换方法用甲醇介绍来完成ACZ催化剂的活性试验。酯交换过程在实验室规模的三个颈部烧瓶中进行。研究了煅烧温度(℃)和催化剂(h)煅烧时间对脂肪酸甲酯(FAME)产率的煅烧时间。结果表明,木棉种子油是值得的,并且可能使用acz催化剂酯交换成生物柴油,最高名称产率为46.67%。

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  • 来源
    《Materials science forum》 |2020年第2020期|87-94|共8页
  • 作者单位

    Chemical Engineering Department Faculty of Engineering WR. Supratman University Surabaya East Java Indonesia 60111;

    Chemical Engineering Department Faculty of Engineering WR. Supratman University Surabaya East Java Indonesia 60111;

    Chemical Engineering Department Faculty of Engineering WR. Supratman University Surabaya East Java Indonesia 60111;

    Chemical Engineering Department Faculty of Engineering WR. Supratman University Surabaya East Java Indonesia 60111;

    Chemical Engineering Department Faculty of Engineering WR. Supratman University Surabaya East Java Indonesia 60111;

    Chemical Engineering Department Faculty of Enginering Catholic Widya Mandala University Surabaya East Java 60114;

    Chemical Engineering Department Faculty of Industrial Technology Sepuluh Nopember Institute of Technology Surabaya East Java Indonesia 60117;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Biodiesel; Kapok seed (Ceiba petandra) oil; CuO- ZnO γ /- Al_2O_3;

    机译:生物柴油;木棉种子(Ceiba Petandra)石油;CUM-ZnOγ/ - AL_2O_3;

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