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Preparation and Characterization of Three-Element Compound Plasticizing Bamboo Fiber-g-Polylactic Acid/Polylactic Acid Composite

机译:三元复合增塑竹纤维-g-聚乳酸/聚乳酸复合材料的制备与表征

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摘要

In view of the phenomenon that the interfacial adhesion between bamboo fiber(BF)and polylactic acid (PLA) is poor and incompatible. Firstly the BF-g-PLA structure with hydrophobicity is synthesized through grafting lactic acid into bamboo fiber, then plasticizing the composite. Three-element compound plasticizer was prepared by mixing glycerol, tributyl citrate and formamide. The effect of the proportion and addition content of three-element plasticizer on the interfacial compatibility of the composite was investigated. The BF-g-PLA/PLA composites were characterized by scanning electron microscopy (SEM), X-ray diffractometry (XRD), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) and rotational rheometer (RC) The composites were tested for their bending properties, tensile properties and water resistance properties using national standards. The experimental results show that the best interfacial adhesion between BF-g-PLA and PLA was obtained when the addition content of glycerol, tributyl citrate, formamide was 10%. At the same time, the flexural strength, elastic modulus, tensile strength and elongation at break of composites all reached the maximum, as well as the thermal stability and the storage modulus.
机译:鉴于竹纤维(BF)与聚乳酸(PLA)的界面附着力差且不相容的现象。首先通过将乳酸接枝到竹纤维中,然后将复合材料增塑,来合成具有疏水性的BF-g-PLA结构。通过将甘油,柠檬酸三丁酯和甲酰胺混合制备三元素复合增塑剂。研究了三元增塑剂的比例和添加量对复合材料界面相容性的影响。通过扫描电子显微镜(SEM),X射线衍射仪(XRD),差示扫描量热法(DSC),热重分析(TGA)和旋转流变仪(RC)对高炉-g-PLA / PLA复合材料进行了表征。其弯曲性能,拉伸性能和耐水性能均采用国家标准。实验结果表明,甘油,柠檬酸三丁酯,甲酰胺的添加量为10%时,BF-g-PLA与PLA的界面粘合性最佳。同时,复合材料的弯曲强度,弹性模量,拉伸强度和断裂伸长率均达到最大值,同时热稳定性和储能模量也达到最大值。

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