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Anti-microbial surfaces: An approach for deposition of ZnO nanoparticles on PVA-Gelatin composite film by screen printing technique

机译:抗菌表面:通过丝网印刷技术在PVA-明胶复合膜上沉积ZnO纳米颗粒的方法

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摘要

Initially micro-organisms get exposed to the surfaces, this demands development of anti-microbial surfaces to inhibit their proliferation. Therefore, herein, we attempt screen printing technique for development of PVA-GE/ZnO nanocomposite (PG/ZnO) films. The synthesis of PG/ZnO nanocomposite includes two steps as: (ⅰ) Coating of Zinc Oxide nanoparticles (ZnO NPs) by poly ethylene glycol in order to be compatible with organic counterparts, (ⅱ) Deposition of coated nanoparticles on the PG film surface. The results suggest the enhancement in anti-microbial activity of PG/ZnO nanocomposite over pure ZnO NPs against both Gram positive Bacillus subtilis and Gram negative Escherichia coli from zone of inhibition. The uniformity in deposition is further confirmed by scanning electron microscopy (SEM) images. The phase identification of ZnO NPs and formation of PG/EnO nanocomposite has been confirmed by X-ray diffraction (XRD) analysis and UV-vis spectroscopy (UV-vis). The Attenuated total reflection Spectroscopy (ATR) analysis indicates the ester bond between PVA and gelatin molecules. The thermal stability of nanocomposite is studied by thermogravimetric analysis (TGA) revealing increase in crystallinity due to ZnO NPs which could be utilized to inhibit the growth of micro-organisms. The tensile strength is found to be higher and percent elongation is double of PG/ZnO nanocomposite than PG composite film.
机译:最初,微生物暴露于表面,这需要开发抗菌表面以抑制其扩散。因此,在本文中,我们尝试使用丝网印刷技术来开发PVA-GE / ZnO纳米复合材料(PG / ZnO)膜。 PG / ZnO纳米复合材料的合成包括两个步骤:(ⅰ)用聚乙二醇涂覆氧化锌纳米颗粒(ZnO NPs),以便与有机对应物相容;(ⅱ)在PG膜表面上沉积涂覆的纳米颗粒。结果表明,从抑制区来看,PG / ZnO纳米复合材料的抗微生物活性优于纯ZnO NPs对革兰氏阳性枯草芽孢杆菌和革兰氏阴性大肠杆菌的抗菌活性。沉积的均匀性通过扫描电子显微镜(SEM)图像进一步证实。 ZnO NPs的相鉴定和PG / EnO纳米复合材料的形成已通过X射线衍射(XRD)分析和紫外可见光谱(UV-vis)得以证实。衰减全反射光谱(ATR)分析表明PVA和明胶分子之间存在酯键。通过热重分析(TGA)研究了纳米复合材料的热稳定性,揭示了由于可用于抑制微生物生长的ZnO NPs导致结晶度增加。发现PG / ZnO纳米复合材料的拉伸强度更高,并且伸长百分比是PG / ZnO纳米复合材料的两倍。

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