Tailoring protective coatings for all-oxide ceramic matrix composites in high temperature-/high heat flux environments and corrosive media

摘要

The application range of porous all-oxide ceramic matrix composites (CMCs) can be significantly extended through deposition of protective coating systems. Typical applications include protection against erosion, wear and foreign object damage as well as a reduced permeability. Environmental barrier coatings (EBC) are mandatory in order to guarantee sufficient lifetime of the CMC components under high temperature-, high heat flux conditions and corrosive attack (combustor liners, thermal protection systems for atmospheric reentry). Limited thermal stability of today's oxide fibers requires additional thermal barrier functionality for EBCs in order to keep the effective CMC bulk temperatures below 1200℃. Depending on the specific application DLR's coating concept for all-oxide CMCs is based on either a single reaction-bonded aluminium oxide (RBAO) coating or a hybrid coating system consisting of a RBAO bond coat followed by an EB-PVD YSZ/FSZ top coat and is highlighted for three case studies. Deposition techniques (magnetron sputtering, MOCVD) alternative to EB-PVD as well as the suitability of fibrous and cellular materials for thick EBC/TBC layers are explored.