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Carbon dioxide corrosion of carbon steel and corrosion inhibition by natural olive leaf extract

机译:碳钢的二氧化碳腐蚀和天然橄榄叶提取物的腐蚀抑制

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摘要

The corrosion of carbon steel in carbon dioxide saturated chloride carbonate solution with and without olive leaf extract at 25 degrees C and 65 degrees C has been studied by linear polarization resistance technique, electrochemical impedance spectroscopy, scanning electron microscopy and Fourier transform infrared spectroscopy. In the absence of olive leaf extract, the corrosion products created under the testing conditions within 24 h at both testing temperatures have no significant protective properties. Measurements for uninhibited systems showed high corrosion current densities and low polarization resistances of carbon steel. Both linear polarization resistance technique and electrochemical impedance spectroscopy measurements reveal that olive leaf extract inhibits the carbon steel corrosion. The addition of a low-concentration olive leaf extract decreases corrosion current densities, increases charge transfer and polarization resistance, resulting in more uniform and smoother steel surfaces. These effects are attributed to the adsorption of olive leaf extract on the carbon steel surface.
机译:通过线性极化电阻技术,电化学阻抗谱,扫描电子显微镜和傅里叶变换红外光谱研究了碳钢在25℃和65℃下有或没有橄榄叶提取物的二氧化碳饱和碳酸氢盐溶液中的腐蚀。在没有橄榄叶提取物的情况下,在两个测试温度下的24小时内的测试条件下产生的腐蚀产物均没有明显的防护性能。对非抑制体系的测量表明,碳钢的腐蚀电流密度高,极化电阻低。线性极化电阻技术和电化学阻抗谱测量均表明,橄榄叶提取物可抑制碳钢腐蚀。添加低浓度橄榄叶提取物会降低腐蚀电流密度,增加电荷转移和极化强度,从而使钢表面更均匀,更光滑。这些作用归因于橄榄叶提取物在碳钢表面上的吸附。

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