Crystalline polycyclic quinone derivatives as organic positive-electrode materials for use in rechargeable lithium batteries

摘要

The performance of 9,10-anthraquinone (AQ), and 5,7.12,14-pentacenetetrone (FT) as active materials for rechargeable lithium batteries was investigated. Positive-electrodes in which AQ and PT were incorporated showed initial discharge capacities of greater than 200mAh/g(AQof PT). The obtained discharge capacities suggest that a multi-electron redox reaction takes place in each derivative. The discharge capacity of the positive-electrode with AQ rapidly decreased during the charge/discharge cycles; however, the positive-electrode with PT showed a relatively good cycle-life performance; it maintained about 80% of the initial capacity even after 100 cycles.