Precipitation behavior of grain boundary M_(23)C_6 and its effect on tensile properties of Ni-Cr-W based superalloy

摘要

Precipitation behavior of grain boundary (GB) M_(23)C_6 and its effect on tensile properties at elevated temperature were investigated systematically in a Ni-Cr-W based superalloy. The results show that the M_(23)C_6 precipitation behavior is influenced obviously by grain boundary character (GBC) and interfacial energy. The E<9 GBs and low angle GBs have low interfacial energy, and no M_(23)C_6 carbide precipitates at these GBs. Plenty of M_(23)C_6 carbide particles precipitate at the large angle GBs with high interfacial energy. The coherent orientation relationship between M_(23)C_6 and the matrix plays an important role on the precipitation morphology of M_(23)C_6. M_(23)C_6 carbides with four typical morphologies distribute at the large angle GBs, including lamellar carbide which grows into the matrix near one side or both sides of the GBs, rod-like carbide and small lamellar carbide both of which grow along GBs. Moreover, the decrease of both tensile and yield strength of the aged alloy is mainly caused by the lamellar M_(23)C_6 carbide breaking. The tensile properties vary irregularly with increasing aging time.