COMPOUNDS OF γ-ZIRCONIUM HYDROGEN PHOSPHATE WITH CADMIUM IONS:PART 1. PREPARATION, THERMAL BEHAVIOR AND X-RAY CHARACTERIZATION OF THE Cd~2+ EXCHANGED AND CdS INTERCALATED MATERIALS

摘要

The exchange of Cd~2+ ions, obtained by several methods, in crystalline γ-zirconium hydrogen phosphate was investigated. The thermal behavior was studied and structural characterization of converted phases was performed. It was found that, after being heated at 320deg.C, when the layered structure is still present, the fully exchanged cadmium material rehydrates in air and returns to the initial phase obtained at room temperature. The molecular intercalate with CdS was also prepared and characterized. Its layered structure and X-ray diffractograms matched those of the starting precursor y-zirconium phos- phate.