SYNTHESIS AND CRYSTAL STRUCTURE OF A NEW OCTAHEDRAL RHENIUM CLUSTER COMPOUND Cs_3Re_6Se_7Br_7H_2O

摘要

New cluster compound Cs_3Re_6Se_7Br_7H_2O was prepared and its crystal struc- ture was solved by single crystal X-ray diffraction (XRD) analysis. Crysta1- lographic data: f triclinic, space group Pl, a = 9.6l3(2), b = ll.569(2), c = l3.344(3) A, a = 90.4l(3), B = 95.48(3), γ = l06.48(3), V = l4l5.6(5) A, Z = 2, D.x = 6.208 g.cm~-3, R(F) = 0.0400, wR(F~2) = 0.0882.