Synthesis of binary and triple carbon nanotubes over Ni/Cu/Al_2O_3 catalyst by chemical vapor deposition

摘要

Novel binary and triple carbon nanotubes (CNTs) with one common catalytic particle encapsulated have been synthesized using Ni/Cu/Al_2O_3 catalyst, which was produced by a sol-gel method. But when using Ni/Al_2O_3 as catalyst, a mass of common CNTs, that is, one CNT with one catalytic particle encapsulated, was obtained. The results showed that copper-element doping to the Ni/Al_2O_3 catalyst played a key role in the synthesis of CNTs, signifying a novel approach to modify the Ni/Al_2O_3 catalyst. Based on the transmission electron microscopy observations, a simple growth mechanism was developed to describe the growth of the binary or triple CNTs, which could be well explained by a diffusion segregation process.