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首页> 外文期刊>Materials Letters >Formation and properties of chalcogenide glasses based on GeS_2-Sb_2S_3-AgI system
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Formation and properties of chalcogenide glasses based on GeS_2-Sb_2S_3-AgI system

机译：基于GeS_2-Sb_2S_3-AgI体系的硫属化物玻璃的形成与性能

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摘要

Novel glasses in GeS_2-Sb_2S_3-AgI system have been prepared by melt-quenching method. A large glass-forming region was found in this novel system, in which almost 60 mol% AgI has been incorporated. The basic physiochemical properties of glass samples were investigated. With the addition of AgI, redshift of short-wavelength absorption edge and distinct drop of the glass transition temperature (T_g) were observed. In addition, a high Ag~+ ion conductivity of 637×10~(-4) S/cm at room temperature was obtained in 55(0.6GeS_2-0.4Sb_2S_3)-45AgI sample, indicating that these glasses have potential application as amorphous solid electrolytes.
机译：采用熔融淬火法制备了GeS_2-Sb_2S_3-AgI体系的新型玻璃。在该新颖系统中发现了大的玻璃形成区域，其中已掺入了近60mol％的AgI。研究了玻璃样品的基本理化性质。加入AgI，观察到短波长吸收边缘的红移和玻璃化转变温度（T_g）的明显下降。此外，在55（0.6GeS_2-0.4Sb_2S_3）-45AgI样品中，室温下的Ag〜+离子电导率很高，为637×10〜（-4）S / cm，表明这些玻璃作为非晶态固体具有潜在的应用前景。电解质。

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  • 来源
    《Materials Letters》 |2014年第1期|203-205|共3页
  • 作者

    Zhuobin Li; Changgui Lin; Guoshun Qu; Laurent Calvez; Shixun Dai; Xianghua Zhang; Tiefeng Xu; Qiuhua Nie;

  • 作者单位

    Laboratory of Infrared Material and Devices, Advanced Technology Research Institute, Ningbo University, Ningbo 315211, China,Ningbo Institute of Material Technology & Engineering, Chinese Academy of Sciences, Ningbo 315201, China;

    Laboratory of Infrared Material and Devices, Advanced Technology Research Institute, Ningbo University, Ningbo 315211, China;

    Laboratory of Infrared Material and Devices, Advanced Technology Research Institute, Ningbo University, Ningbo 315211, China;

    Laboratoire des Verres et Ceramiques, UMR-CNRS 6512, Campus de Beaulieu, Universite de Rennes 1, 35042 Rennes Cedex, France;

    Laboratory of Infrared Material and Devices, Advanced Technology Research Institute, Ningbo University, Ningbo 315211, China;

    Laboratoire des Verres et Ceramiques, UMR-CNRS 6512, Campus de Beaulieu, Universite de Rennes 1, 35042 Rennes Cedex, France;

    Laboratory of Infrared Material and Devices, Advanced Technology Research Institute, Ningbo University, Ningbo 315211, China;

    Laboratory of Infrared Material and Devices, Advanced Technology Research Institute, Ningbo University, Ningbo 315211, China,Ningbo Institute of Material Technology & Engineering, Chinese Academy of Sciences, Ningbo 315201, China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Amorphous materials; Electrical properties; Optical materials and properties;

    机译：非晶态材料;电气性能;光学材料和性能;

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