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Ultrathin SnO nanosheets as anode materials for rechargeable lithium-ion batteries

机译:超薄SnO纳米片作为可再充电锂离子电池的负极材料

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摘要

SnO ultrathin nanosheets with a highly pure crystal phase were successfully prepared via a simple and effective hydrothermal process, using tin dichloride dihydrate (SnCl_2 • 2H_2O) as a stannous source in the presence of hexamethylenetetramine (HMT). SEM and TEM images showed that the obtained SnO products are uniform and ultrathin nanosheets. The electrochemical properties results indicated that the obtained SnO nanosheets exhibited excellent discharge capacity, the reversible capacity was 559 mAh g~(-1) after 20 cycles, and the SnO nanosheets retain high capacity even at high discharge current densities. The enhanced performance was attributed to the unique structure of ultrathin SnO nanosheets and highly pure crystal phase.
机译:通过二水合二氯化锡(SnCl_2•2H_2O)作为亚锡源,在六亚甲基四胺(HMT)存在下,通过简单有效的水热工艺成功制备了具有高纯晶相的SnO超薄纳米片。 SEM和TEM图像表明,所获得的SnO产物是均匀且超薄的纳米片。电化学性能结果表明,所获得的SnO纳米片表现出优异的放电容量,20次循环后可逆容量为559 mAh g〜(-1),即使在高放电电流密度下,SnO纳米片仍保持高容量。性能的提高归因于超薄SnO纳米片的独特结构和高纯度的晶相。

著录项

  • 来源
    《Materials Letters》 |2014年第1期|200-203|共4页
  • 作者单位

    Institute of Nanochemistry and Nanobiology, School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, PR China,State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai 200433, PR China;

    Institute of Nanochemistry and Nanobiology, School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, PR China;

    Institute of Nanochemistry and Nanobiology, School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, PR China;

    Institute of Nanochemistry and Nanobiology, School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, PR China;

    Institute of Nanochemistry and Nanobiology, School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, PR China;

    School of Environmental Science and Engineering, Tongji University, Shanghai 200092, PR China;

    Institute of Nanochemistry and Nanobiology, School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, PR China;

    Institute of Nanochemistry and Nanobiology, School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, PR China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    SnO; Nanosheets; Hexamethylenetetramine (HMT); Lithium-ion batteries;

    机译:SnO;纳米片;六亚甲基四胺(HMT);锂离子电池;

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