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Beneficial Effects Of Nitrogen On Austenite Antibacterial Stainless Steels

机译:氮对奥氏体抗菌不锈钢的有益作用

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Nitrogen is a significant alloying element in austenite stainless steels. The aim of this paper is to evaluate the effects of nitrogen on the microstructure and properties of austenite antibacterial stainless steels. Two austenite antibacterial stainless steels containing copper and different nitrogen concentration (0.02 and 0.08 wt%, respectively) were fabricated. The microstructures and composition analysis were carried out using field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), atomic force microscopy (AFM) and Auger electron spectroscopy (AES). The epsilon copper-rich precipitates are spherical and less than 20 nm in size, with a cube-on-cube orientation relationship with the matrix. They are dispersed on the steel surface with a mean space of about 200 nm. Nitrogen cannot only improve the antibacterial property but enhance significantly the corrosion resistance in chloride media. Nitrogen compensates the harmful effect of epsilon copper precipitates on the corrosion resistance. The nitrogen concentration in the surface of N-2 steel is four times as much as in the surface of N-l steel. Nitrogen enrichment in the steel surface improves the corrosion resistance. The presence of higher nitrogen increases the strength and decreases the ductility of austenite antibacterial stainless steel, which could be related to the variation of stacking-fault energy associated with nitrogen concentration.
机译:氮是奥氏体不锈钢中的重要合金元素。本文的目的是评估氮对奥氏体抗菌不锈钢的组织和性能的影响。制备了两种含铜和不同氮浓度(分别为0.02和0.08 wt%)的奥氏体抗菌不锈钢。使用场发射扫描电子显微镜(FE-SEM),透射电子显微镜(TEM),原子力显微镜(AFM)和俄歇电子能谱(AES)进行微观结构和成分分析。富含ε铜的沉淀是球形的,尺寸小于20 nm,与基质之间具有立方对立方的定向关系。它们分散在钢表面上,平均间距约为200 nm。氮不仅可以改善抗菌性能,而且可以显着提高氯化物介质中的耐腐蚀性。氮补偿了ε铜沉淀物对耐蚀性的有害影响。 N-2钢表面的氮浓度是N-1钢表面的四倍。钢表面富氮改善了耐腐蚀性。较高氮的存在会提高奥氏体抗菌不锈钢的强度并降低其延展性,这可能与氮浓度相关的堆垛层错能量变化有关。

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