Preparation and Structure of Ba_2Ti_9O_(20) and BaTi_4O_9 Ceramics Derived from Sol-Gel Powders

摘要

Ba_2Ti_9O_(20) (B2T9) and BaTi_4O_9 (BT4) ceramics have been fabricated using sol-gel technique. The sol-gel derived powder was produced from barium acetate and butyl titanate using acetic acid as solvent. The as-prepared powders were then calcined at different temperatures ranging from 600° to 1200℃. After that, the powder was pressed into pellets and further sintered at different temperatures ranging from 1250℃ to 1380℃. XRD characterization and Raman spectroscopy showed that after calcining the sol-gel powder at 900℃ for 2 h and sintering the pressed pellets at 1330℃ for 4 h, triclinic B2T9 and orthorhom-bic BT4ceramics could be obtained. The dielectric constant and Q-value are 35 and 1910 at 6.1 GHz.