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Electrical Conductivity in Alkali Iron Phosphate Glasses

机译:碱式磷酸铁玻璃的电导率

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摘要

The electrical properties of 10M_2O-36Fe_2O_3-54P_2O_5 (M=Li, Na and K) glasses were studied in the temperature range from 323 to 573 K. Non-linear Arrhenius behavior was observed for all the samples examined. It was shown that in both high- and low-temperature ranges, the replacement of Li, Na and K would result in decreases in both the dc conductivity and the activation energy. Analysis of the relationship of the parameters included in the Arrhenius equation, activation energy and the pre- exponential factor for each sample, preliminary explanations for these experimental phenomena have been presented.
机译:在323至573 K的温度范围内研究了10M_2O-36Fe_2O_3-54P_2O_5(M = Li,Na和K)玻璃的电性能。所有样品均观察到非线性阿伦尼乌斯行为。结果表明,在高温和低温范围内,Li,Na和K的替代都会导致直流电导率和活化能的降低。通过分析每个样品的Arrhenius方程,活化能和指数因子之间的关系,对这些实验现象进行了初步解释。

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