Activation of H_2 and Et_3SiH by the Borinium Cation [Mes_2B]~+: Avenues to Cations [MesB(μ-H)_2(μ-Mes)BMes]~+ and [H_2B(μ-H)(μ-Mes)B(μ-Mes)(μ-H)BH_2]~+

摘要

Reaction of dihydrogen and the borinium cation salt [Mes(2)B][B(C6F5)(4)] gave an arene-stabilized mesityl-borenium cation, which isotopically scrambles HD. Similarly, reaction with triethylsilane gave the diboranium cation [MesB(mu-H)(2)(mu-Mes)BMes](+) featuring three bridge-bonds between two boron centers. Reaction of same (Mes(2)BH)(2) with Bronsted acid also afforded the same diboranium whereas the corresponding reaction with (MesBH(2))(2) yielded the triboron cation [H2B(mu-H)(mu-Mes)B(mu-Mes)(mu-H)BH2](+).