Auxiliary-Directed, Asymmetric Complexation and Metal-Promoted Higher-Order Cycloaddition in the Cycloheptatriene Series

James H. Rigby; Priyantha Sugathapala; Mary Jane Heeg

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Auxiliary-Directed, Asymmetric Complexation and Metal-Promoted Higher-Order Cycloaddition in the Cycloheptatriene Series

机译：环庚三烯系列中的辅助定向，不对称络合和金属促进的高阶环加成

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The feasibility of diastereoface-selective com-plexation of substituted cycloheptatrienes has been demonstrated, and the asymmetry of the resultant complexes can be translated into [6π + 4π] and [6π + 2π] cycloadducts with complete integrity.

机译：已经证明了取代的环庚烯的非对映体选择性络合的可行性，并且所得络合物的不对称性可以完全完整性转化为[6π+4π]和[6π+2π]环加合物。

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《Journal of the American Chemical Society》 |1995年第34期|p.8851-8852|共2页
作者
James H. Rigby; Priyantha Sugathapala; Mary Jane Heeg;
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作者单位

Department of Chemistry, Wayne State University Detroit, Michigan 48202-3489;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
原文格式 PDF
正文语种 eng
中图分类化学;
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入库时间 2022-08-18 03:26:22

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1. LIPASE-MEDIATED RESOLUTION AND HIGHER-ORDER CYCLOADDITION OF SUBSTITUTED TRICARBONYL (ETA(6)-CYCLOHEPTATRIENE)CHROMIUM(0) COMPLEXES [J] . Rigby JH., Sugathapala P. Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 1996,第30期

机译：脂酶介导的取代三苯甲酰基（ETA（6）-环庚三烯）铬（0）配合物的拆分和高阶循环
2. Benzannulation via Sequential Metal-Promoted Higher-Order Cycloaddition-Ramberg-Baecklund Rearrangement [J] . James H. Rigby, Namal C. Warshakoon The Journal of Organic Chemistry . 1996,第22期

机译：通过顺序金属促进的高阶环加成-Ramberg-Baecklund重排进行苯环化
3. Novel Stereochemistry, Reactivity, and Stability of an Arsenic Heterocycle in a Metal-Promoted Asymmetric Cycloaddition Reaction [J] . Mengtao Ma, Sumod A. Pullarkat, Yongxin Li Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2007,第22期

机译：金属促进的不对称环加成反应中砷杂环的新型立体化学，反应性和稳定性
4. Chirality Switching in an Asymmetric Strecker Reaction Caused by Higher-Order Structural Differences between Rare Earth Metal Complexes [C] . Tsuyoshi Mita, Nobuki Kato, Motomu Kanai Symposium on Organometallic Chemistry . 2006

机译：在稀土金属配合物之间的高阶结构差异引起的不对称斑块反应中的手性转换
5. I. Photochemical catalytic [6pi + 2pi] higher-order cycloadditions. II. Toward the development of a chiral catalyst for chromium(0) higher-order cycloadditions. III. Synthetic studies toward a synthesis of taxol: Investigation of an intramolecular cycloaddition approach to the taxane core. [D] . Mann, Larry W. 2002

机译：I.光化学催化的[6pi + 2pi]高阶环加成。二。走向手性催化剂的铬（0）高阶环加成反应的发展。三，合成紫杉醇的合成研究：紫杉烷核心分子内环加成方法的研究。
6. Formal (4+1) Cycloaddition of Methylenecyclopropanes with 7-Aryl-135-cycloheptatrienes by Triple Gold(I) Catalysis [O] . Yahui Wang, Michael E Muratore, Zhouting Rong, -1

机译：三重金（I）催化亚甲基环丙烷与7-芳基-135-环庚烯的正式（4 + 1）环加成反应
7. Formal (4+1) Cycloaddition of Methylenecyclopropanes with 7-Aryl-1,3,5-cycloheptatrienes by Triple Gold(I) Catalysis [O] . Wang, Y, Muratore, M.E., Rong, Z, 2014

机译：三重金（I）催化亚甲基环丙烷与7-芳基-1,3,5-环庚烯的正式（4 + 1）环加成反应

Auxiliary-Directed, Asymmetric Complexation and Metal-Promoted Higher-Order Cycloaddition in the Cycloheptatriene Series

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