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首页> 外文期刊>Journal of the American Chemical Society >Radical Reactions of a Stable N-Heterocyclic Germylene:EPR Study and DFT Calculation
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Radical Reactions of a Stable N-Heterocyclic Germylene:EPR Study and DFT Calculation

机译：稳定的N-杂环亚甲基的自由基反应：EPR研究和DFT计算

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摘要

Although many reactions of stable unsaturated iV-heterocyclic divalent compounds of group 14 elements(1-4)have now been described,the radical chemistry of these compounds is relatively little known.4"7 Several radical adducts of silylene 2 with free radicals of different chemical nature(TEMPO,P(O)(O~iPr)_2,~(centre dot)Re(CO)_5,~(centre dot)MoCp(CO)_2,~(centre dot)WCp(CO)_3,-CH_2Ph)have been studied by EPR and DFT calculations.
机译：尽管现在已经描述了第14组元素（1-4）的稳定的不饱和iV杂环二价化合物的许多反应，但这些化合物的自由基化学知之甚少。4“ 7甲硅烷基2的几种自由基加成物具有不同的自由基化学性质（TEMPO，P（O）（O〜iPr）_2，〜（中心点）Re（CO）_5，〜（中心点）MoCp（CO）_2，〜（中心点）WCp（CO）_3，-已通过EPR和DFT计算研究了CH_2Ph）。

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  • 来源
    《Journal of the American Chemical Society》 |2005年第23期|p.8248-8249|共2页
  • 作者

    Boris Tumanskii; Pauline Pine; Yitzhak Apeloig; Nicholas J.Hill; Robert West;

  • 作者单位

    Department of Chemistry and the Lise Meitner-Minerva Center for Computational Quantum Chemistry,Technion-Israel Institute of Technology,Haifa 32000,Israel,and Department of Chemistry,University of Wisconsin,Madison,Wisconsin 53706;

    Department of Chemistry and the Lise Meitner-Minerva Center for Computational Quantum Chemistry,Technion-Israel Institute of Technology,Haifa 32000,Israel,and Department of Chemistry,University of Wisconsin,Madison,Wisconsin 53706;

    Department of Chemistry and the Lise Meitner-Minerva Center for Computational Quantum Chemistry,Technion-Israel Institute of Technology,Haifa 32000,Israel,and Department of Chemistry,University of Wisconsin,Madison,Wisconsin 53706;

    Department of Chemistry and the Lise Meitner-Minerva Center for Computational Quantum Chemistry,Technion-Israel Institute of Technology,Haifa 32000,Israel,and Department of Chemistry,University of Wisconsin,Madison,Wisconsin 53706;

    Department of Chemistry and the Lise Meitner-Minerva Center for Computational Quantum Chemistry,Technion-Israel Institute of Technology,Haifa 32000,Israel,and Department of Chemistry,University of Wisconsin,Madison,Wisconsin 53706;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
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