Self-Assembly of Supramolecular Chiral Insulated Molecular Wire

摘要

Recently,there has been a growing interest in the development of conjugated polymer(CP)molecular wires in view of their theoretical importance for the exploration of new physical properties arising from the pi-electron delocalization and for the potential applications to molecular electronics and sensory signal amplification.CPs are often described as one-dimensional molecular wires in current nanotechnology programs,but the relevant physics is usually two- or three-dimensional due to their strong aggregation tendency both in solution and solid phases.This makes it a challenging subject to fabricate CP molecular wires on a single-molecular scale.