All-Catalytic,Efficient,and Asymmetric Synthesis of alpha,omega-Diheterofunctional Reduced Polypropionates via 'One-Pot' Zr-Catalyzed Asymmetric Carboalumination Pd-Catalyzed Cross-Coupling Tandem Process

Tibor Novak; Ze Tan; Bo Liang; Ei-ichi Negishi

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All-Catalytic,Efficient,and Asymmetric Synthesis of alpha,omega-Diheterofunctional Reduced Polypropionates via 'One-Pot' Zr-Catalyzed Asymmetric Carboalumination Pd-Catalyzed Cross-Coupling Tandem Process

机译：通过“一锅” Zr催化的不对称碳铝化钯催化的交叉偶联串联工艺全催化，高效且不对称地合成α，ω-二异官能还原的丙酸酯

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We report herein a highly efficient method for the synthesis of stereoisomerically pure(>=99% ee and >=50/1 dr)alpha,omega-dihetero-functional reduced polypropionates,the essential features of which are represented by the conversion of inexpensive(

机译：我们在此报告了一种高效的立体异构纯（> = 99％ee和> = 50/1 dr）α，ω-二异官能取代的丙酸酯的合成方法，其基本特征由廉价的（从苯经Zr催化的不对称碳铝键合（ZACA反应）和Pd催化原位生成的乙烯基化过程中分两步将

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《Journal of the American Chemical Society》 |2005年第9期|p.2838-2839|共2页
作者
Tibor Novak; Ze Tan; Bo Liang; Ei-ichi Negishi;
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作者单位

Herbert C.Brown Laboratories of Chemistry,Purdue University,560 Oval Drive,West Lafayette,Indiana 47907;

Herbert C.Brown Laboratories of Chemistry,Purdue University,560 Oval Drive,West Lafayette,Indiana 47907;

Herbert C.Brown Laboratories of Chemistry,Purdue University,560 Oval Drive,West Lafayette,Indiana 47907;

Herbert C.Brown Laboratories of Chemistry,Purdue University,560 Oval Drive,West Lafayette,Indiana 47907;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
原文格式 PDF
正文语种 eng
中图分类化学;
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入库时间 2022-08-18 03:23:48

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1. An Efficient and General Method for the Synthesis of alphe,omicron-Difunctional Reduced Polypropionates by Zr-Catalyzed Asymmetric Carboalumination: Synthesis of the Scyphostatin Side Chain [J] . Ze Tan, Ri-ichi Negishi Angewandte Chemie . 2004,第22期

机译：Zr催化不对称碳铝催化合成Alph，micron-双官能团还原性丙酸酯的高效通用方法：Scyphostatin侧链的合成
2. Efficient and selective synthesis of 6,7-dehydrostipiamide via Zr-catalyzed asymmetric carboalumination and Pd-catalyzed cross-coupling of organozincs [J] . Zeng XZ, Zeng FX, Negishi E Organic letters . 2004,第19期

机译：通过Zr催化的不对称碳铝键合和Pd催化的有机锌交叉偶联有效和选择性地合成6,7-脱氢stipiamide
3. Efficient and Selective Synthesis of Siphonarienolone and Related Reduced Polypropionates via Zr-Catalyzed Asymmetric Carboalumination [J] . Marina Magnin-Lachaux, Ze Tan, Bo Liang, Organic letters . 2004,第9期

机译：通过Zr催化的不对称碳铝铝高效选择性合成虹吸烯酮和相关的还原性丙酸酯
4. Efficient Catalytic Asymmetric Synthesis of alpha-Substitnted Phenyloxyacetyloxy and Aroyloxy Phosphonates [C] . Liu Hui, Xiao Wenjing International Symposium on Pesticide and Environmental Safety . 2007

机译：高效催化不对称合成α-替代苯氧乙酰氧基和岭氧基膦酸盐
5. Part I. One-pot synthesis of secondary alcohols and one-pot asymmetric synthesis of secondary propargylic alcohols. Part II. Redox isomerization of secondary propargylic alcohols to enones. Part III. Synthesis study towards C9-C14 fragment of (+)-discodermolide. Part IV. Asymmetric synthesis of anti, anti-stereotriad building blocks for polypropionate natural products [D] . Xie, Qiuzhe 2007

机译：第一部分：仲醇的一锅法合成和仲炔丙醇的一锅法不对称合成。第二部分仲炔丙醇的氧化还原异构化为烯酮。第三部分（+）-discodermolide C9-C14片段的合成研究。第四部分聚丙烯酸酯天然产物的抗，抗立体三环构建基的不对称合成
6. Efficient and Stereoselective Synthesis of Yellow Scale Pheromone via Alkyne Haloboration Zr-Catalyzed Asymmetric Carboalumination of Alkenes (ZACA Reaction) and Pd-Catalyzed Tandem Negishi Coupling [O] . Zhaoqing Xu, Ei-ichi Negishi* -1

机译：通过炔烃卤化Zr催化的烯烃不对称碳铝化（ZACA反应）和Pd催化的串联Negishi偶联高效且立体选择性地合成黄色鳞状信息素。
7. All-Catalytic, Efficient, and Asymmetric Synthesis of a, w-Diheterofunctional Reduced Polypropionates via One-Pot Zr-Catalyzed Asymmetric Carboalumination-Pd-Catalyzed Cross-Coupling Tandem Process [O] . -1

机译：通过单壶Zr催化的不对称碳酸化-PD催化的交叉耦合串联工艺A，W-Δα的全催化，高效和不对称合成的A，W-ΔFoctionopate的聚丙烯酸盐

All-Catalytic,Efficient,and Asymmetric Synthesis of alpha,omega-Diheterofunctional Reduced Polypropionates via 'One-Pot' Zr-Catalyzed Asymmetric Carboalumination Pd-Catalyzed Cross-Coupling Tandem Process

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