Synthesis of an Aluminum Spirocyclic Hybrid with an Inorganic B_2O_3 and an Organic C_3N_2 Core

摘要

In recent years the synthesis of organic-inorganic hybrid materials has become an important target.This was impressively shown by I.Manners who discovered the ROP of silaferro-cenophanes which provide access to poly(ferrocenylsilanes).Today ferrocenophanes with different main group elements in the bridging position are known,including a ferrocenophane with aluminum.Since then,aluminum containing organic-inorganic hybrid materials is a fascinating subject.