Giant Heterometallic Cu_(17)Mn_(28) Cluster with T_d Symmetry and High-Spin Ground State

Wen-Guo Wang; Ai-Ju Zhou; Wei-Xiong Zhang; Ming-Liang Tong; Xiao-Ming Chen; Motohiro Nakano; Christopher C. Beedle; David N. Hendrickson

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Giant Heterometallic Cu_(17)Mn_(28) Cluster with T_d Symmetry and High-Spin Ground State

机译：具有T_d对称性和高自旋基态的巨型杂金属Cu_（17）Mn_（28）团簇

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摘要

We have established an approach to generate a giant heterometallic mixed-valent Cu~Ⅰ/Cu~Ⅱ/Mn~Ⅱ/Mn~Ⅲ/Mn~Ⅳ cluster which contains an unprecedented adamantane-like Mn_(28) core connected wholly by Mn_4O_4 cubane units and exhibits unusual magnetic properties.

机译：我们已经建立了一种生成巨大的杂金属混合价Cu〜Ⅰ/ Cu〜Ⅱ/ Mn〜Ⅱ/ Mn〜Ⅲ/ Mn〜Ⅳ团簇的方法，该团簇包含一个空前的金刚烷样Mn_（28）核，该核通过Mn_4O_4完全连接并表现出不同寻常的磁性。

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来源
《Journal of the American Chemical Society》 |2007年第5期|p.1014-1015|共2页
作者
Wen-Guo Wang; Ai-Ju Zhou; Wei-Xiong Zhang; Ming-Liang Tong; Xiao-Ming Chen; Motohiro Nakano; Christopher C. Beedle; David N. Hendrickson;
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作者单位

MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, People's Republic of China;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
原文格式 PDF
正文语种 eng
中图分类化学;
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入库时间 2022-08-18 03:21:08

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Giant Heterometallic Cu_(17)Mn_(28) Cluster with T_d Symmetry and High-Spin Ground State

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