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首页> 外文期刊>Journal of the American Chemical Society >Guest-dependent High Pressure Phenomena In A Nanoporous Metal-organicrnframework Material
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Guest-dependent High Pressure Phenomena In A Nanoporous Metal-organicrnframework Material

机译:纳米多孔金属有机框架材料中依赖客体的高压现象

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Nanoporous metal-organic framework (MOF) materials display a wide range of functional properties with important technological, industrial, and environmental applications in areas such as molecular sensing and strategic gas storage/separation. Their well documented structural complexities can be expected to yield unprecedented pressure-induced phenomena, with the further potential for coupling of the host-guest properties afforded by their open structures and the small molecule pressure-transmitting fluids often used in high-pressure science. Moreover, compared to traditional solid state materials these open (i.e., low density) systems are likely to be "soft", with perturbations to the structure and functionality at less extreme pressures: pressures such as may be routinely encountered in practical applications.
机译:纳米多孔金属有机框架(MOF)材料在分子传感和战略性气体存储/分离等领域具有重要的技术,工业和环境应用,显示出广泛的功能特性。可以很好地证明其结构复杂性会产生空前的压力诱发现象,其开放结构和高压科学中经常使用的小分子压力传递流体提供了进一步耦合客体特性的潜力。而且,与传统的固态材料相比,这些开放(即低密度)系统可能是“软的”,在较小的极端压力下会扰动结构和功能:在实际应用中通常会遇到这样的压力。

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