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Iron Catalysis In Organic Chemistry: Reactions And Applications

机译:有机化学中的铁催化:反应与应用

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摘要

Iron catalysis is an area of synthetic chemistry that has undergone an explosive revival in the past five years. Although compounds such as Fe(CO)_5 and ferrocene are recognized by most chemists as the signature molecules of organotransition metal chemistry, coordination and organometallic compounds of iron have played a lesser role in homogeneous catalysis as compared to precious metals, especially as applied to organic methodology. This book is a timely and authoritative review of this reemerging area of chemistry. As noted in the Preface by Plietker, increased attention to sustainability has resulted in a resurrection of interest in iron compounds. Given the ubiquity of iron in biology and its role in heterogeneous catalysis, particularly industrial nitrogen fixation, it should not be surprising that iron should exhibit a rich catalytic chemistry in the realm of organic synthesis.
机译:铁催化是合成化学领域,在过去五年中经历了爆炸性的复兴。尽管大多数化学家都将诸如Fe(CO)_5和二茂铁之类的化合物识别为有机过渡金属化学的标志分子,但与贵金属相比,铁的配位化合物和有机金属化合物在均相催化中的作用较小,特别是应用于有机金属时方法。这本书是对这个新兴的化学领域的及时而权威的评论。正如普利特克(Plietker)在序言中指出的那样,对可持续性的日益关注导致对铁化合物的兴趣复活。鉴于铁在生物学中的普遍性及其在非均相催化(特别是工业固氮)中的作用,铁在有机合成领域应展现出丰富的催化化学特性就不足为奇了。

著录项

  • 来源
    《Journal of the American Chemical Society》 |2009年第10期|3788-3789|共2页
  • 作者

    Paul J. Chirik;

  • 作者单位
  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
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  • 入库时间 2022-08-18 03:16:52

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