High-Efficiency Green Organic Light-Emitting Devices Utilizing Phosphorescent Bis-cyclometalated Alkynylgold(Ⅲ)Complexes

摘要

A new phosphorescent material of cyclometalated alkynylgold(Ⅲ) complex, [Au(2,5-F_2C_6H_3-C∧N∧C)(C≡C-C_6H_4N(C_6H_5)_2-p)] (1) (2,5-F_2C_6H_3-HC∧N∧CH = 2,6-diphenyl-4-(2,5-difluorophenyl)pyri-dine), has been synthesized, characterized, and its device performance investigated. This luminescent gold(lll) complex was found to exhibit rich PL and EL properties and has been utilized as phosphorescent dopants of OLEDs. At an optimized dopant concentration of 4%, a device with a maximum external quantum efficiency (EQE) of 11.5%, corresponding to a current efficiency of 37.4 cd/A and a power efficiency of 26.2 Im/W, has been obtained. Such a high EQE is comparable to that of lr(ppy)_3-based devices. The present work suggests that the alkynylgold(lll) complex is a promising phosphorescent material in terms of both efficiency and thermal stability, with the additional advantages of its relatively inexpensive cost and low toxicity.